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A system is described by the Hamiltonian $\mathcal{H}=\mathcal{H}_0 + \epsilon \mathcal{H}_1$. $\mathcal{H}_0$ has a doubly-degenerate ground state of zero energy. The corresponding eigenkets are $\left |1\right>$ and $\left |2\right>$. $\mathcal{H}_1$ has the property that $\left< 1|\mathcal{H}_1|1\right>=\left<2|\mathcal{H}_1|2\right> = 0$ and $\left<1|\mathcal{H}_1|2\right> = a$. Finally, $\epsilon$ is a small parameter.
(a) Find the two lowest energy states and the corresponding eigenkets of the Hamiltonian $\mathcal{H}$ accurate to the lowest non-vanishing order in $\epsilon$.
(b) Write down a general expression for the ket $\left |\psi(t)\right>$ in terms of the eigenkets found above.
(c) Calculate the probability of finding the system in the state $\left |1\right>$ at time t if it was in the state $\left |2\right>$ at t = 0.
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Answer
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(a) The Hamiltonian $\mathcal{H}$ projected on the Hilbert space spanned by $\left |1\right>$ and $\left |2\right>$ can be written in the form of the 2 × 2 matrix
(1)Let $a=|a|e^{i\theta/2}$. Diagonalizing the above matrix, we find that the two lowest energies are Es = |a| and Ea = -|a|. The corresponding eigenstates are
(2)(b) The answer is ($\hbar$ = 1):
(3)(c) It is easy to see that
(4)In addition,
(5)whence
(6)and so the probability in question is
(7)
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